SIMBAD references

CH₃CN is a species observed to be much more abundant in ultracompact hot molecular cores (UCHCs) than can be accounted for by dark cloud gas phase chemistry. The close proximity of UCHCs to newly formed OB stars suggests that an impinging far ultraviolet (FUV) radiation field might contribute to the chemical processing at the core margins. In this paper, the photochemistry of gas phase CH₃CN formation is explored assuming an enhanced FUV radiation field interacts with dense neutral material evaporated from grain mantle ices. We are able to show that high CH₃CN/CH₃OH abundance ratios can be generated from CH₃OH and NH₃ precursors in such a photon-dominated margin as a realistic alternative to a grain surface origin. We show that the observed CH₃CN/CH₃OH column density ratio towards the UCHC in G34.3+0.15 can be interpreted as arising from photochemical generation of CH₃CN in the gas phase.