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2005ApJS..159..314A - Astrophys. J., Suppl. Ser., 159, 314-330 (2005/August-0)

The electron excited ultraviolet spectrum of HD: cross sections and transition probabilities.

AJELLO J., PALLE P.V., ABGRALL H., ROUEFF E., BHARDWAJ A. and GUSTIN J.

Abstract (from CDS):

We have analyzed the high-resolution ultraviolet (UV) emission spectrum of molecular deuterium hydride (HD) excited by electron impact at 100 eV under optically thin, single-scattering experimental conditions. The high-resolution spectrum (FWHM=160 mÅ) spans the wavelength range from 900 to 1650 Å and contains the two Rydberg series of HD: 1Σ+u1sσ, npσ(B, B', B'', n=2, 3, 4)⟶X 1Σ+g and 1Π+u1sσ, npπ(C, D, D', D'', n=2, 3, 4, 5)⟶X1Σ+g. A model spectrum of HD, based on newly calculated transition probabilities and line positions including rovibrational coupling for the strongest band systems, B 1Σ+u-X 1Σ+g, B '1Σ+u-X 1Σ+g, C 1Πu-X 1Σ+g, and D 1Πu-X 1Σ+g, is in excellent agreement with observed intensities. The cross sections for direct excitation at 100 eV of the B 1Σ+u, B' 1Σ+u, C 1Πu, and D 1Πu states were derived from a model analysis of the experimental fluorescence spectrum to the ground state. The absolute cross section values for excitation to the B 1Σ+u, B' 1Σ+u, C 1Πu, and D 1Πu states were found to be (2.57±0.26)x10–17, (0.22±0.06)x10–17, (2.54±0.25)x10–17, and (0.17±0.04)x10–17 cm2, respectively. We have also determined the dissociative excitation cross sections at 100 eV for the emission of Lyα at 1216 Å and Lyβ at 1025 Å lines, which are (7.98±1.12)x10–18 and (0.40±0.10)x10–18 cm2, respectively. The summed excitation function of the closely spaced pair of lines, H Lyα and D Lyα, resulting from dissociative excitation of HD, has been measured from the threshold to 800 eV and is analytically modeled with a semiempirical relation. The model cross sections are in good agreement with the corrected Lyα cross sections of Möhlmann et al. up to 2 keV. Based on measurements of H, D (2s) production cross section values by Möhlmann et al., the H, D (n=2) cross section is estimated to be 1.6x10–17 cm2 at 100 eV.

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Journal keyword(s): Molecular Data

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