The purpose of this study is to investigate the distributions of the isomeric molecules HCN and HNC and estimate their abundance ratio in the protostellar core
Cha-MMS1 located in Chamaeleon I. The core was mapped in the J=1-0 rotational lines of HCN, HNC, and HN
13C. The column densities of H
13CN, HN
13C, H
15NC and NH
3 were estimated towards the centre of the core. The core is well delineated in all three maps. The kinetic temperature in the core, derived from the NH
3 (1, 1) and (2, 2) inversion lines, is 12.1 ±0.1K. The HN
13C/H
13CN column density ratio is between 3 and 4, i.e. similar to values found in several other cold cores. The HN
13C/H
15NC column density ratio is ∼7. In case no
15N fractionation occurs in HNC (as suggested by recent modelling results), the HNC/HN
13C abundance ratio is in the range 30-40, which indicates a high degree of
13C fractionation in HNC. Assuming no differential
13C fractionation the HCN and HNC abundances are estimated to be ∼7x10
–10 and ∼2x10
–9, respectively, the former being nearly two orders of magnitude smaller than that of NH
3. Using also previously determined column densities in
Cha-MMS1, we can put the most commonly observed nitrogenous molecules in the following order according to their fractional abundances: χ(NH
3)>χ(HC
3N)>χ(HNC)>χ(HCN)>χ(N
2H
+). The relationships between molecular abundances suggest that
Cha-MMS1 represents an evolved chemical stage, experiencing at present the ``late-time'' cyanopolyyne peak. The possibility that the relatively high HNC/HCN ratio derived here is only valid for the
13C isotopic substitutes cannot be excluded on the basis of the present and other available data.