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2012A&A...543A..46C - Astronomy and Astrophysics, volume 543A46-46 (2012/7-1)

The submillimeter-wave spectrum of the doubly deuterated species of methyl formate HCOOCD2H.

COUDERT L.H., MARGULES L., HUET T.R., MOTIYENKO R.A., MOLLENDAL H. and GUILLEMIN J.-C.

Abstract (from CDS):

Astronomical surveys of interstellar molecules, such as those that will be available with the very sensitive ALMA telescope, require preliminary laboratory investigations of the microwave and submillimeter-wave spectra of new molecular species to identify these in the interstellar media. We build a linelist that should allow us to detect HCOOCD2H, provided it is present in the interstellar media in a suitable concentration. The experimental spectra of HCOOCD2H have been recorded in the microwave and submillimeter-wave energy range. Line frequencies were analyzed using an internal axis method-like treatment taking into account the CD2H internal rotation. 5933 lines of HCOOCD2H have been assigned and their frequencies were reproduced with a unitless standard deviation of 1.6. A linelist with calculated frequencies and intensities was built and spans the 50-660GHz spectral region. The frequency accuracy is better than 0.1MHz. The pure rotation spectrum of the CD2H-methyl formate isotopolog (HCOOCD2H) has been observed in laboratory for the first time.

Abstract Copyright: ∼

Journal keyword(s): methods: data analysis - surveys - catalogs - molecular data - techniques: spectroscopic

VizieR on-line data: <Available at CDS (J/A+A/543/A46): table3.dat table6.dat table10.dat>

Simbad objects: 1

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