SIMBAD references

2018ApJ...858...36C - Astrophys. J., 858, 36-36 (2018/May-1)

Isomeric and isotopic effects on the electronic spectrum of C60+-He: consequences for astronomical observations of C60+.

CAMPBELL E.K. and MAIER J.P.

Abstract (from CDS):

Laboratory measurements are reported that enable a more accurate determination of the characteristics of the near-infrared absorptions of C60+ below 10 K. These data were obtained by photofragmentation of C60+–He complexes in a cryogenic trap. Asymmetry in the profiles of the observed 9577 and 9632 Å absorption bands of C60+–He is caused by the attachment of the weakly bound helium atom to hexagonal or pentagonal faces of C60+. The implication is that the FWHM of the bands in the electronic spectrum of C60+ below 10 K is 1.4 Å. The effect of 13C isotopes on the C60+ electronic spectrum is experimentally evaluated by measurement of 12C60+–He, 13C112C59+–He, and 13C212C58+–He. Data on the 9365 Å absorption band indicate a wavelength shift of about 0.3 Å between the former and latter. This result is consistent with models used to interpret the vibrational isotope effect in the Raman spectrum of neutral C60. The influence of 13C isotopes on the 9348, 9365, 9428, 9577, and 9632 Å diffuse interstellar bands is expected to be minor considering other broadening factors that affect astronomical observations. The presented data also provide more accurate relative intensities of the five interstellar bands attributed to C60+.

Abstract Copyright: © 2018. The American Astronomical Society. All rights reserved.

Journal keyword(s): ISM: molecules

Simbad objects: 4

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