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2024ApJ...976..114L - Astrophys. J., 976, 114 (2024/November-3)

Measurements of the Reaction Rate Coefficients of Atomic Hydrogen with Astrochemical Anions: CN– and C3N–.

LOCHMANN C., PURUSHU MELATH S., WILD R., YURTSEVER E., MARTIN SANTA DARIA A., GONZALEZ-SANCHEZ L., GIANTURCO F.A. and WESTER R.

Abstract (from CDS):

We present the temperature-dependent reaction rate coefficients of CN– and C3N– with atomic hydrogen in the temperature range from 7 to 290 K, measured in a 16-pole radio-frequency ion trap. The rate of C3N– with H steadily increases toward lower temperatures, while the rate coefficients for the CN– + H system show a sudden change around 160 K. Fits to the data were performed to determine temperature-dependent reaction rate coefficients. The fits reveal a rate coefficient of $4.1{(3)\times {10}^{-10}(T/300)}^{-0.31(6)}$ cm3 s–1 for C3N– + H. For CN–, we determined a rate coefficient for the temperature regime below 160 K of $3.2{(4)\times {10}^{-10}(T/300)}^{-0.31(11)}$ cm3 s–1. Given our present results, higher rate coefficients than previously reported must be assumed for the modeling of cold interstellar environments involving these H atom reactions.

Abstract Copyright: © 2024. The Author(s). Published by the American Astronomical Society.

Journal keyword(s): Interstellar clouds - Laboratory astrophysics - Ion-neutral reactions

Simbad objects: 3

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