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2024MNRAS.52710726P - Mon. Not. R. Astron. Soc., 527, 10726-10736 (2024/February-1)

ExoMol line lists - LII. Line lists for the methylidyne cation (CH+).

PEARCE O., YURCHENKO S.N. and TENNYSON J.

Abstract (from CDS):

Comprehensive and accurate rovibronic line lists for the X 1Σ+ and A 1Π states of 12C1H+ and 13C1H+ which should be applicable up to temperatures of 5000 K are presented. Available empirical potential energy curves and high-level ab initio dipole and transition dipole moment curves are used with the program LEVEL to compute rovibronic energy levels and Einstein A coefficients. Λ-doubling is incorporated into the energy levels and A-coefficients involving the A 1Π state using an empirical method. For 12C1H+, line positions are improved by using both laboratory and astronomical observational spectra as input to the MARVEL (Measured Active Rotational-Vibrational Energy Levels) procedure. The 12C1H+ line list contains 1505 states and 34 194 transitions over the frequency range of 0-33 010 cm–1 (λ > 300 nm). Comparisons with observed astronomical and laboratory spectra give very good agreement. The PYT CH+ line lists and partition functions are available from the ExoMol database at www.exomol.com.

Abstract Copyright: © 2023 The Author(s). Published by Oxford University Press on behalf of Royal Astronomical Society.

Journal keyword(s): molecular data - opacity - exoplanets - planets and satellites: atmospheres - ISM: molecules

Simbad objects: 3

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