1999A&A...351..273A

The formation of lithium lines in the atmosphere of C-rich giants is discussed. LTE and NLTE approximations are used to model lithium lines in the spectra of super Li-rich AGB stars. The system of equations of the statistical balance of neutral Li in plane-parallel model atmospheres is solved for a 20-level atom model. JOLA and line-by-line models of molecular absorption are used to compute synthetic spectra as well as the opacity in the frequencies of bound-bound and bound-free transitions of the lithium lines. Curves of growth and synthetic spectra are computed in LTE and NLTE for several model atmospheres of different T_eff and C/O ratios for four lithium absorptions, namely: the λ4603, λ6104, λ6708 and λ8126Å Li I lines. The sensitivity of NLTE effects on T_eff and the C/O ratio is discussed. We found that NLTE mainly affects the resonance line doublet (λ6708) while the impact of NLTE effects on the lithium subordinate lines, formed in the inner regions of C-rich giant atmospheres, is rather weak. Therefore the use of these lines is recommended for Li determination in AGB stars. However, in no case can we properly account for the formation of Li lines in AGB stars until sphericity, velocity stratifications, dust, chromospheres and other related phenomena, which are in fact present in AGB star atmospheres, are considered. Our results are used to derive Li abundances in three super-Li rich C-stars taking into account NLTE effects. Finally, the net Li yield from this class of stars into the interstellar medium is reconsidered.