2001ApJS..133..345W

We present high-resolution (FWHM ∼0.4-1.8 km.s^–1) spectra, obtained with the AAT UHRF, the McDonald Observatory 2.7 m coudé spectrograph, and/or the KPNO coudé feed, of interstellar K I absorption toward 54 Galactic stars. These new K I spectra reveal complex structure and narrow, closely blended components in many lines of sight. Multicomponent fits to the line profiles yield estimates for the column densities, line widths, and velocities for 319 individual interstellar cloud components. The median component width (FWHM) and the true median separation between adjacent components are both ≲1.2 km.s^–1. The median and maximum individual component K I column densities, about 4x10¹⁰ and 10¹² cm^–2, correspond to individual component hydrogen column densities of about 2x10²⁰ and 10²¹ cm^–2 and E(B-V)∼0.03 and 0.17, respectively. If T is typically ∼100 K, then at least half the individual components have subsonic internal turbulent velocities. We also reexamine the relationships between the column densities of K I, Na I, C I, Li I, H_tot, H₂, and CH. The four trace neutral species exhibit essentially linear relationships with each other over wide ranges in overall column density. If C is uniformly depleted by 0.4 dex, then Li, Na, and K are each typically depleted by 0.6-0.7 dex. The total line of sight values for N(K I) and N(Na I) show roughly quadratic dependences on N(H_tot), but the relationships for the ensemble of individual clouds could be significantly steeper. These quadratic (or steeper) dependences appear to rule out significant contributions to the ionization from cosmic rays, X-rays, and/or charge exchange with C II in most cases. Charge exchange with negatively charged large molecules may often be more important than radiative recombination in neutralizing most singly ionized atomic species in cool H I clouds, however–suggesting that the true n_e, n_H, and thermal pressures may be significantly smaller than the values estimated by considering only radiative recombination. Both N(CH) and N(H₂) are nearly linearly proportional to N(K I) and N(Na I) [except for 10¹⁵ cm^–2≲N(H₂)≲10¹⁹ cm^–2, over which H₂ makes the transition to the self-shielded regime]. Those relationships appear also to hold for many individual components and component groups, suggesting that high-resolution spectra of K I and Na I can be very useful for interpreting lower resolution molecular data. The scatter about all these mean relationships is generally small (≲0.1-0.2 dex), if certain consistently ``discrepant'' sight lines are excluded–suggesting that both the relative depletions and the relative ionization of Li, C, Na, and K are generally within factors of 2 of their mean values. Differences noted for sight lines in Sco-Oph, in the Pleiades, near the Orion Trapezium, and in the LMC and SMC may be due to differences in the strength and/or shape of the ambient radiation fields, perhaps amplified by the effects of charge transfer with large molecules.