2002ApJ...580L.133M

Very Large Telescope (VLT) L-band spectra of six carbon stars in the Large Magellanic Cloud are presented. The stars show absorption bands at 3.1 µm (HCN and C₂H₂), and 3.8 µm, which is probably due to C₂H₂. Two LMC stars show strong 3.5 µm HCN absorption. The equivalent widths of the 3.1 µm and 3.8 µm bands are systematically larger in LMC carbon stars than in carbon stars in the solar neighborhood. Moreover, the ratio of the equivalent widths of the 3.8 and 3.1 µm bands is much larger in the LMC, suggesting a higher ratio of n(C₂H₂)/n(HCN). The stronger absorption bands are in contrast to the assumption that if the elemental abundances are scaled from the carbon star's abundances in the solar neighbor, the abundances of these molecules are less at lower metallicity. We argue for a systematically larger C/O ratio in LMC carbon stars. In the Galactic carbon stars n(C)/n(O)~1.05-1.1 on average; our chemical model shows that the stronger molecular bands in the LMC carbon stars could be explained with n(C)/n(O)>1.2. The higher C/O ratio can also explain the higher ratio of n(C₂H₂)/n(HCN) in LMC stars than in the solar neighborhood.