2005AJ....129..567G

We present 0.5-8.0 keV Chandra observations of six bright quasars that represent extrema in quasar emission-line properties–three quasars each with small and large blueshifts of the C IV emission line with respect to the systemic redshift of the quasars. Supplemented with seven archival Chandra observations of quasars that met our selection criteria, we investigate the origin of this emission-line phenomenon in the general context of the structure of quasars. We find that the quasars with the largest C IV blueshifts show evidence, from joint spectral fitting, for intrinsic X-ray absorption (N_H∼10²²/cm2). Given the lack of accompanying C IV absorption, this gas is likely to be highly ionized and may be identified with the shielding gas in the disk-wind paradigm. Furthermore, we find evidence for a correlation of α_UV, the ultraviolet spectral index, with the hardness of the X-ray continuum; an analysis of independent Bright Quasar Survey data from the literature supports this conclusion. This result points to intrinsically red quasars having systematically flatter hard X-ray continua without evidence for X-ray absorption. We speculate on the origins of these correlations of X-ray properties with both C IV blueshift and α_UVand discuss the implications for models of quasar structure.