2005MNRAS.356.1099P

Published interpretations of the relative intensity variations of the unidentified infrared bands (UIBs) and their underlying continuum are discussed. An alternative model is proposed, in which a single carrier for both emits (a) mostly a continuum when it is electronically excited by photons (visible or UV), or (b) exclusively the UIBs, when only chemical energy is deposited by H capture on its surface, inducing only nuclear vibrations. The bands will dominate in atomic H regions but will be overcome by thermal continuum radiation when the ambient field is strong but lacks dissociating photons (900-1100Å). The model applies to photodissociation regions as well as to limbs of molecular clouds in the interstellar medium and agrees quantitatively with recent satellite observations. It gives indications on atomic H density and UIB intensity provided the ambient radiation field is known. It invokes no chemical, electronic, structural or size change to interpret the observed intensity variations.