2007ApJ...659..642L

We fit the Doppler profiles of the He-like triplet complexes of O VII and N VI in the X-ray spectrum of the O star ζ Pup, using XMM-Newton RGS data collected over ∼400 ks of exposure. We find that they cannot be well fit if the resonance and intercombination lines are constrained to have the same profile shape. However, a significantly better fit is achieved with a model incorporating the effects of resonance scattering, which causes the resonance line to become more symmetric than the intercombination line for a given characteristic continuum optical depth τ_*. We discuss the plausibility of this hypothesis, as well as its significance for our understanding of Doppler profiles of X-ray emission lines in O stars.