2011ApJ...730...97M

We discuss the effect of chemical separation as matter freezes at the base of the ocean of an accreting neutron star, and argue that the retention of light elements in the liquid acts as a source of buoyancy that drives a slow but continual mixing of the ocean, enriching it substantially in light elements, and leading to a relatively uniform composition with depth. We first consider the timescales associated with different processes that can redistribute elements in the ocean, including convection, sedimentation, crystallization, and diffusion. We then calculate the steady-state structure of the ocean of a neutron star for an illustrative model in which the accreted hydrogen and helium burn to produce a mixture of O and Se. Even though the H/He burning produces only 2% oxygen by mass, the steady-state ocean has an oxygen abundance more than 10 times larger, almost 40% by mass. Furthermore, we show that the convective motions transport heat inward, with a flux of ~0.2 MeV/nucleon for an O-Se ocean, heating the ocean and steepening the outward temperature gradient. The enrichment of light elements and heating of the ocean due to compositionally driven convection likely have important implications for carbon ignition models of superbursts.