2011ApJ...740...93S

We present a laboratory study of silicate glasses of astrophysically relevant compositions including olivines, pyroxenes, and melilites. With emphasis on the classic Si-O stretching feature near 10 µm, we compare infrared spectra of our new samples with laboratory spectra on ostensibly similar compositions, and also with synthetic silicate spectral data commonly used in dust modeling. Several different factors affect spectral features including sample chemistry (e.g., polymerization, Mg/Fe ratio, oxidation state, and Al-content) whereas different sample preparation techniques lead to variations in porosity, density, and water content. The convolution of chemical and physical effects makes it difficult to attribute changes in spectral parameters to any given variable. It is important that detailed chemical and structural characterization be provided along with laboratory spectra. In addition to composition and density, we measured the glass transition temperatures for the samples which place upper limits on the formation and/or processing temperatures of these solids in space. Popular synthetically generated optical functions do not have spectral features that match any of our glass samples. However, the ∼10 µm feature generated by the synthetic data rarely exactly matches the shape and peak position of astronomically observed silicate features. Our comparison with the synthetic spectra allows astronomers to determine likely candidates among our glass samples for matching astronomical observations.