2012ApJ...759L..21G

We search high-resolution and high-quality VLT/UVES optical spectra of the hot R Coronae Borealis star DY Cen for electronic transitions of the C₆₀ molecule and diffuse interstellar bands (DIBs). We report the non-detection of the strongest C₆₀ electronic transitions (e.g., those at ∼3760, 3980, and 4024 Å). The absence of C₆₀ absorption bands may support recent laboratory results, which show that the ∼7.0, 8.5, 17.4, and 18.8 µm emission features seen in DY Cen–and other similar objects with polycyclic-aromatic-hydrocarbon-like dominated IR spectra–are attributable to proto-fullerenes or fullerene precursors rather than to C₆₀. DIBs toward DY Cen are normal for its reddening; the only exception is the DIB at 6284 Å (possibly also the 7223 Å DIB) which is found to be unusually strong. We also report the detection of a new broad (FWHM ∼ 2 Å) and unidentified feature centered at ∼4000 Å. We suggest that this new band may be related to the circumstellar proto-fullerenes seen at infrared wavelengths.