2013ApJ...767...81M

We report the detection of hydrogen chloride, HCl, in diffuse molecular clouds on the line of sight toward the star-forming region W31C (G10.6-0.4). The J = 1-0 lines of the two stable HCl isotopologues, H³⁵Cl and H³⁷Cl, are observed using the 1b receiver of the Heterodyne Instrument for the Far-Infrared (HIFI) on board the Herschel Space Observatory. The HCl line is detected in absorption, over a wide range of velocities associated with diffuse clouds along the line of sight to W31C. The analysis of the absorption strength yields a total HCl column density of a few 10¹³/cm2, implying that HCl accounts for ∼0.6% of the total gas-phase chlorine, which exceeds the theoretical model predictions by a factor of ∼6. This result is comparable to those obtained from the chemically related species H₂Cl⁺ and HCl⁺, for which large column densities have also been reported on the same line of sight. The source of discrepancy between models and observations is still unknown; however, the detection of these Cl-bearing molecules provides key constraints for the chlorine chemistry in the diffuse gas.