2013ApJS..209...38K

A spectral line survey of the oxygen-rich red supergiant VY Canis Majoris was made between 279 and 355 GHz with the Submillimeter Array (SMA). Two hundred twenty-three spectral features from 19 molecules (not counting isotopic species of some of them) were observed, including the rotational spectra of TiO, TiO₂, and AlCl for the first time in this source. The parameters and an atlas of all spectral features are presented. Observations of each line with a synthesized beam of ∼0.''9, reveal the complex kinematics and morphology of the nebula surrounding VY CMa. Many of the molecules are observed in high-lying rotational levels or in excited vibrational levels. From these, it was established that the main source of the submillimeter-wave continuum (dust) and the high-excitation molecular gas (the star) are separated by about 0.''15. Apparent coincidences between the molecular gas observed with the SMA, and some of the arcs and knots observed at infrared wavelengths and in the optical scattered light by the Hubble Space Telescope are identified. The observations presented here provide important constraints on the molecular chemistry in oxygen-dominated circumstellar environments and a deeper picture of the complex circumstellar environment of VY CMa.