2018MNRAS.474.4594B

Query : 2018MNRAS.474.4594B

2018MNRAS.474.4594B - Mon. Not. R. Astron. Soc., 474, 4594-4602 (2018/March-2)

Interstellar dehydrogenated PAH anions: vibrational spectra.

BURAGOHAIN M., PATHAK A., SARRE P. and GOUR N.K.

Abstract (from CDS):

Interstellar polycyclic aromatic hydrocarbon (PAH) molecules exist in diverse forms depending on the local physical environment. Formation of ionized PAHs (anions and cations) is favourable in the extreme conditions of the interstellar medium (ISM). Besides in their pure form, PAHs are also likely to exist in substituted forms; for example, PAHs with functional groups, dehydrogenated PAHs etc. A dehydrogenated PAH molecule might subsequently form fullerenes in the ISM as a result of ongoing chemical processes. This work presents a density functional theory (DFT) calculation on dehydrogenated PAH anions to explore the infrared emission spectra of these molecules and discuss any possible contribution towards observed IR features in the ISM. The results suggest that dehydrogenated PAH anions might be significantly contributing to the 3.3 µm region. Spectroscopic features unique to dehydrogenated PAH anions are highlighted that may be used for their possible identification in the ISM. A comparison has also been made to see the size effect on spectra of these PAHs.

Abstract Copyright: © 2017 The Author(s) Published by Oxford University Press on behalf of the Royal Astronomical Society

Journal keyword(s): astrochemistry - molecular processes - ISM: lines and bands - ISM: molecules

Status at CDS : Large table(s) will be appraised for possible ingestion in VizieR.

Simbad objects: 1

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Number of rows : 1
N Identifier Otype ICRS (J2000)
RA 		ICRS (J2000)
DEC 		Mag U Mag B Mag V Mag R Mag I Sp type #ref
1850 - 2026 		#notes
1 TMC-1 MoC 04 41 45.9 +25 41 27           ~ 1872 0

Query : 2018MNRAS.474.4594B

Basic data :
TMC-1 -- Molecular Cloud
Other object types: otypes_help 		PoC (MLB,[MOH94]), MoC (TMC), Cld (HCL)
ICRS coord. (ep=J2000) : 		04 41 45.9 +25 41 27 [ ] D 1983ApJ...264..517M
FK4 coord. (ep=B1950 eq=1950) : 		04 38 42.0 +25 35 45 [ ]
Gal coord. (ep=J2000) : 		174.3852 -13.4312 [ ]
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Hierarchy : number of linked objects
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HCL 2 MLB 3-28 TMC-1 [MOH94] 6

References (1872 between 1850 and 2026) (Total 1872)
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