2020A&A...636A..68D

We present results from a set of simulations using a fully coupled three-dimensional (3D) chemistry-radiation-hydrodynamics model and investigate the effect of transport of chemical species by the large-scale atmospheric flow in hot Jupiter atmospheres. We coupled a flexible chemical kinetics scheme to the Met Office Unified Model, which enables the study of the interaction of chemistry, radiative transfer, and fluid dynamics. We used a newly-released "reduced" chemical network, comprising 30 chemical species, that was specifically developed for its application in 3D atmosphere models. We simulated the atmospheres of the well-studied hot Jupiters HD 209458b and HD 189733b which both have dayside-nightside temperature contrasts of several hundred Kelvin and superrotating equatorial jets. We find qualitatively quite different chemical structures between the two planets, particularly for methane (CH₄), when advection of chemical species is included. Our results show that consideration of 3D chemical transport is vital in understanding the chemical composition of hot Jupiter atmospheres. Three-dimensional mixing leads to significant changes in the abundances of absorbing gas-phase species compared with what would be expected by assuming local chemical equilibrium, or from models including 1D - and even 2D - chemical mixing. We find that CH₄, carbon dioxide (CO₂), and ammonia (NH₃) are particularly interesting as 3D mixing of these species leads to prominent signatures of out-of-equilibrium chemistry in the transmission and emission spectra, which are detectable with near-future instruments.