2020ApJ...904..110D

Rotational transitions in vibrationally excited AlO and TiO-two possible precursors of dust-were observed in the 300 GHz range (1 mm wavelength) toward the oxygen-rich asymptotic giant branch (AGB) stars R Dor and IK Tau with ALMA, and vibrationally excited AlO was observed toward the red supergiant VY CMa with the SMA. The J = 11 - 10 transition of TiO in the v = 1 and 2 levels and the N = 9 - 8 transition in the v = 2 level of AlO were identified toward R Dor, the J = 11 - 10 line of TiO was identified in the v = 1 level toward IK Tau, and two transitions in the v = 1 and 2 levels of AlO were identified toward VY CMa. The newly derived high vibrational temperature of TiO and AlO in R Dor of 1800 ± 200 K and prior measurements of the angular extent confirm that the majority of the emission is from a region within <=2R_* of the central star. A full radiative transfer analysis of AlO in R Dor yielded a fractional abundance of ∼3% of the solar abundance of Al. From a similar analysis of TiO a fractional abundance of ∼78% of the solar abundance of Ti was found. The observations provide indirect evidence that TiO is present in a rotating disk close to the star. Further observations in the ground and excited vibrational levels are needed to determine whether AlO, TiO, and TiO₂ are seeds of the Al₂O₃ dust in R Dor, and perhaps in the gravitationally bound dust shells in other AGB stars with low mass-loss rates.