2021MNRAS.503.2973C

In this work, we analyse soft X-ray emission due to mass accretion on to compact stars and its effects on the time-scale to reach chemical equilibrium of eventual surrounding astrophysical ices exposed to that radiation. Reaction time-scales due to soft X-ray in water-rich and pure ices of methanol, acetone, acetonitrile, formic acid, and acetic acid were determined. For accretion rates in the range {dot}m=10^–12-10^–8 M_☉ yr^–1 and distances in the range 1-3 LY from the central compact objects, the time-scales lie in the range 10-10⁸ yr, with shorter time-scales corresponding to higher accretion rates. Obtained time-scales for ices at snow-line distances can be small when compared to the lifetime (or age) of the compact stars, showing that chemical equilibrium could have been achieved. Time-scales for ices to reach chemical equilibrium depend on X-ray flux and, hence, on accretion rate, which indicates that systems with low accretion rates may not have reached chemical equilibrium.