2022ApJ...934...97F

We report results for a complete sample of 10 luminous radio-quiet quasars with large C IV equivalent widths (EW ≥ 150 Å). For 8/10 we performed Chandra snapshot observations. We find that, in addition to the enhanced C IV line EW, their He II and Mg II lines are enhanced, but the C III] line is not. Their X-ray emission is substantially stronger than expected from their ultraviolet luminosity. Additionally, these large C IV EW quasars show small C IV blueshifts and possibly low Eddington ratios, suggesting that they are “extreme low Eigenvector 1 (EV1)” quasars. The mean excess He II EW is well matched by radiation pressure compression (RPC) photoionization models, with the harder α_ox ionizing spectrum. However, these results do not reproduce well the enhancement pattern of the C IV, Mg II, and C III] EWs, or the observed high C IV/Mg II ratio. RPC calculations indicate that the C IV/Mg II line ratio is an effective metallicity indicator, and models with subsolar-metallicity gas and a hard ionizing continuum reproduce well the enhancement pattern of all four ultraviolet lines. We find that the C IV/Mg II line ratio in quasars is generally correlated with the excess X-ray emission. Extremely high EV1 quasars are characterized by high metallicity and suppressed X-ray emission. The underlying mechanism relating gas metallicity and X-ray emission is not clear but may be related to radiation-pressure-driven disk winds, which are enhanced at high metallicity, and consequent mass loading reducing coronal X-ray emission.