2022MNRAS.509.3677P

6.7 GHz methanol masers are the brightest of class II methanol masers that are regarded as excellent signposts in the formation of young massive stars. We present here a molecular line study of 68 6.7 GHz methanol maser hosts chosen from the Methanol Multibeam survey catalogue, which have MALT90 data available. We performed (1) pixel-by-pixel study of 9 methanol maser sources that have high signal-to-noise ratio and (2) statistical study taking into account the entire 68 sources. We estimated the molecular column densities and abundances of N₂H⁺(1-0), HCO⁺(1-0), HCN(1-0), and HNC(1-0) lines. The derived abundances are found to be in congruence with the typical values found towards high-mass star-forming regions. We derived the column density and abundance ratios between these molecular species as an attempt to unveil the evolutionary stage of methanol maser sources. We found the column density and abundance ratio of HCN to HNC to increase and that of N₂H⁺ to HCO⁺ to decline with source evolution, as suggested by the chemical models. The HCN/HNC, N₂H⁺/HCO⁺, HNC/HCO⁺, and N₂H⁺/HNC ratios of the methanol maser sources are consistent with them being at a later evolutionary state than quiescent phase and possibly protostellar phase, but at an earlier stage than H II regions and photo-dominated regions.