2023A&A...677L..13A

We report the detection of large hydrocarbon cycles toward several cold dense clouds. We observed four sources (L1495B, Lupus-1A, L483, and L1527) in the Q band (31-50 GHz) using the Yebes 40 m radiotelescope. Using the line stack technique, we find statistically significant evidence of benzonitrile (C₆H₅CN) in L1495B, Lupus-1A, and L483 at levels of 31.8σ, 15.0σ, and 17.2σ, respectively, while there is no hint of C₆H₅CN in the fourth source, L1527. The column densities derived are in the range (1.7-3.8) × 10¹¹ cm^–2, which is somewhat below the value derived toward the cold dense cloud TMC-1. When we simultaneously analyze all the benzonitrile abundances derived toward cold clouds in this study and in the literature, a clear trend emerges in that the higher the abundance of HC₇N, the more abundant C₆H₅CN is. This indicates that aromatic cycles are especially favored in those interstellar clouds where long carbon chains are abundant, which suggests that the chemical processes that are responsible for the formation of linear carbon chains are also behind the synthesis of aromatic rings. We also searched for cycles other than benzonitrile, and found evidence of indene (C₉H₈), cyclopentadiene (C₅H₆), and 1-cyano cyclopentadiene (1-C₅H₅CN) at levels of 9.3σ, 7.5σ, and 8.4σ, respectively, toward L1495B, which shows the strongest signal from C₆H₅CN. The relative abundances between the various cycles detected in L1495B are consistent - within a factor of three - with those previously found in TMC-1. It is therefore likely that not only C₆H₅CN but also other large aromatic cycles are abundant in clouds rich in carbon chains.