2023AJ....165...84M

TOI-270 d is a temperate sub-Neptune discovered by the Transiting Exoplanet Survey Satellite (TESS) around a bright (J = 9.1 mag) M3V host star. With an approximate radius of 2 R_⊕ and equilibrium temperature of 350 K, TOI-270 d is one of the most promising small exoplanets for atmospheric characterization using transit spectroscopy. Here we present a primary transit observation of TOI-270 d made with the Hubble Space Telescope Wide Field Camera 3 (WFC3) spectrograph across the 1.126-1.644 μm wavelength range, and a 95% credible upper limit of 8.2 × 10^–14 erg s^–1 cm^–2 Å^–1 arcsec^–2 for the stellar Lyα emission obtained using the Space Telescope Imaging Spectrograph. The transmission spectrum derived from the TESS and WFC3 data provides evidence for molecular absorption by a hydrogen-rich atmosphere at 4σ significance relative to a featureless spectrum. The strongest evidence for any individual absorber is obtained for H₂O, which is favored at 3σ significance. When retrieving on the WFC3 data alone and allowing for the possibility of a heterogeneous stellar brightness profile, the detection significance of H₂O is reduced to 2.8σ. Further observations are therefore required to robustly determine the atmospheric composition of TOI-270 d and assess the impact of stellar heterogeneity. If confirmed, our findings would make TOI-270 d one of the smallest and coolest exoplanets to date with detected atmospheric spectral features.