2023ApJ...948...88W

With the start of JWST observations, mid-infrared (MIR) emission features from polycyclic aromatic hydrocarbons (PAHs), H₂ rotational lines, fine structure lines from ions, and dust continuum will be widely available tracers of gas and star formation rate (SFR) in galaxies at various redshifts. Many of these tracers originate from dust and gas illuminated by UV photons from massive stars, so they generally trace both SFR and gas to varying degrees. We investigate how MIR spectral features from 5-35 μm and photometry from 3.4-250 μm correlate with SFR and molecular gas. In general, we find MIR emission features (i.e., PAHs and H₂ rotational lines) trace both CO and SFR better than CO and SFR trace one another. H₂ lines and PAH features correlate best with CO. Fine structure lines from ions correlate best with SFR. The [S III] lines at 18.7 and 33.5 μm, in particular, have a very tight correlation with SFR, and we use them to calibrate new single-parameter MIR tracers of SFR that have negligible metallicity dependence in our sample. The 17 μm/7.7 μm PAH feature ratio increases as a function of CO emission which may be evidence of PAH growth or neutralization in molecular gas. The degree to which dust continuum emission traces SFR or CO varies as a function of wavelength, with continuum between 20 and 70 μm better tracing SFR, while longer wavelengths better trace CO.