2024AJ....167..130L

The purpose of this work is to describe the assumptions built into the X-ray spectrum fitting software XSPEC for the calculation of element abundances and emission measure of a plasma and to describe the effects when those assumptions are not accurate. The ratio of electron density to hydrogen density in XSPEC is fixed at a constant. The correct ratio can be calculated from the ionization states of the elements. We show the constant value used in XSPEC is valid to within ≃3.5% for a solar-abundance plasma. For a plasma that deviates from solar abundance, e.g., hydrogen-poor or heavy-element-rich plasmas such as those found in the ejecta of supernova remnants, this ratio can be smaller by factors of 0.1-0.001. The hydrogen emission measure, defined by integral of electron density times hydrogen density over plasma volume, is derived from the norm in XSPEC, but one needs to include the hydrogen abundance factor. For other elements, the emission measures are the XSPEC values multiplied by the element abundance factors. Using the correct electron-to-hydrogen ratio and emission measures, we show the correct electron density is smaller by the square root of the correct electron density ratio divided by the XSPEC value. Element densities and total masses (for given distance and volume) are larger by the abundance factors divided by the above square root. Because hydrogen-poor plasmas occur in the ejecta of Type Ia supernova remnants, previously estimated element masses from X-ray spectra are likely to be significantly underestimated.