2024ApJ...974...20W

We use deep Spitzer mid-infrared spectroscopic maps of radial strips across three nearby galaxies with well-studied metallicity gradients (M101, NGC 628, and NGC 2403) to explore the physical origins of the observed deficit of polycyclic aromatic hydrocarbons (PAHs) at subsolar metallicity (i.e., the PAH-metallicity relation or PZR). These maps allow us to trace the evolution of all PAH features from 5-18 μm as metallicity decreases continuously from solar (Z_⊙) to 0.2 Z_⊙. The total PAH-to-dust luminosity ratio remains relatively constant until reaching a threshold of ∼ 2/3 Z_⊙, below which it declines smoothly but rapidly. The PZR has been attributed to preferential destruction of the smallest grains in the hard radiation environments found at low metallicity. In this scenario, a decrease in emission from the shortest-wavelength PAH features is expected. In contrast, we find a steep decline in long-wavelength power below Z_⊙, especially in the 17 μm feature, with the shorter-wavelength PAH bands carrying an increasingly large fraction of power at low metallicity. We use newly developed grain models to reproduce the observed PZR trends, including these variations in fractional PAH feature strengths. The model that best reproduces the data employs an evolving grain size distribution that shifts to smaller sizes as metallicity declines. We interpret this as a result of inhibited grain growth at low metallicity, suggesting continuous replenishment in the interstellar medium is the dominant process shaping the PAH grain population in galaxies.