2025ApJ...979..157K

We increase the spectroscopic completeness of the 100 pc white dwarf sample in the Sloan Digital Sky Survey footprint with 840 additional spectra. Our spectroscopy is 86% complete for white dwarfs hotter than T_eff = 5000 K, where Hα remains visible and provides reliable constraints on the atmospheric composition. We identify 2108 DA white dwarfs with pure hydrogen atmospheres, and show that ultramassive DA white dwarfs with M ≥ 1.1 M_⊙ are an order of magnitude less common below 10,000 K. This is consistent with a fraction of them getting stuck on the crystallization sequence due to ²²Ne distillation. In addition, there are no ultramassive DA white dwarfs with M ≥ 1.1M_⊙ and T_eff ≤ 6000 K in our sample, likely because Debye cooling makes them rapidly fade away. We detect a significant trend in the fraction of He atmosphere white dwarfs as a function of temperature; the fraction increases from 9% at 20,000 K to 32% at 6000 K. This provides direct evidence of convective mixing in cool DA white dwarfs. Finally, we detect a relatively tight sequence of low-mass DQ white dwarfs in color-magnitude diagrams for the first time. We discuss the implications of this tight DQ sequence, and conclude with a discussion of the future prospects from the upcoming Ultraviolet Transient Astronomy Satellite mission and the large-scale multi-fiber spectroscopic surveys.