2025ApJ...984L..36W


Query : 2025ApJ...984L..36W

2025ApJ...984L..36W - Astrophys. J., 984, L36 (2025/May-1)

Discovery of the Seven-ring Polycyclic Aromatic Hydrocarbon Cyanocoronene (C24H11CN) in GOTHAM Observations of TMC-1.

WENZEL G., GONG S., XUE C., CHANGALA P.B., HOLDREN M.S., SPEAK T.H., STEWART D.A., FRIED Z.T.P., WILLIS R.H.J., BERGIN E.A., BURKHARDT A.M., BYRNE A.N., CHARNLEY S.B., LIPNICKY A., LOOMIS R.A., SHINGLEDECKER C.N., COOKE I.R., McCARTHY M.C., REMIJAN A.J., WENDLANDT A.E. and McGUIRE B.A.

Abstract (from CDS):

We present the synthesis and laboratory rotational spectroscopy of the seven-ring polycyclic aromatic hydrocarbon (PAH) cyanocoronene (C24H11CN) using a laser-ablation-assisted cavity-enhanced Fourier transform microwave spectrometer. A total of 71 transitions were measured and assigned between 6.8 and 10.6 GHz. Using these assignments, we searched for emission from cyanocoronene in the Green Bank Telescope (GBT) Observations of TMC-1: Hunting Aromatic Molecules project observations of the cold dark molecular cloud TMC-1 using the 100 m GBT. We detect a number of individually resolved transitions in ultrasensitive X-band observations and perform a Markov Chain Monte Carlo analysis to derive best-fit parameters, including a total column density of $N({{\rm{C}}}_{24}{{\rm{H}}}_{11}{\rm{CN}})=2.6{9}_{-0.23}^{+0.26}\times 1{0}^{12}\,{{\rm{cm}}}^{-2}$ at a temperature of $6.0{5}_{-0.37}^{+0.38}\,$K. A spectral stacking and matched filtering analysis provides a robust 17.3σ significance to the overall detection. The derived column density is comparable to that of cyano-substituted naphthalene, acenaphthylene, and pyrene, defying the trend of decreasing abundance with increasing molecular size and complexity found for carbon chains. We discuss the implications of the detection for our understanding of interstellar PAH chemistry and highlight major open questions and next steps.

Abstract Copyright: © 2025. The Author(s). Published by the American Astronomical Society.

Journal keyword(s): Astrochemistry - Polycyclic aromatic hydrocarbons - Interstellar medium - Interstellar molecules - Radio astronomy - Radio spectroscopy - High resolution spectroscopy - Microwave spectroscopy - Rotational spectroscopy - Cavity-enhanced Fourier-transform - Surveys

Simbad objects: 1

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Number of rows : 1
N Identifier Otype ICRS (J2000)
RA
ICRS (J2000)
DEC
Mag U Mag B Mag V Mag R Mag I Sp type #ref
1850 - 2026
#notes
1 TMC-1 MoC 04 41 45.9 +25 41 27           ~ 1872 0

Query : 2025ApJ...984L..36W

Basic data :
TMC-1 -- Molecular Cloud
Other object types:
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PoC (MLB,[MOH94]), MoC (TMC), Cld (HCL)
ICRS coord. (ep=J2000) :
04 41 45.9 +25 41 27 [ ] D 1983ApJ...264..517M
FK4 coord. (ep=B1950 eq=1950) :
04 38 42.0 +25 35 45 [ ]
Gal coord. (ep=J2000) :
174.3852 -13.4312 [ ]
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Hierarchy : number of linked objects
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HCL 2 MLB 3-28 TMC-1 [MOH94] 6

References (1872 between 1850 and 2026) (Total 1872)
Simbad bibliographic survey began in 1850 for stars (at least bright stars) and in 1983 for all other objects (outside the solar system).
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