2025ApJ...991..228H

A powerful technique to trace the signatures of the first stars is through the metal enrichment in concentrated reservoirs of hydrogen, such as the damped Lyα absorbers (DLAs) in the early Universe. We conducted a survey aimed at discovering DLAs along sight lines to high-z quasars in order to measure element abundances at z > 4. Here we report our first results from this survey for 10 DLAs with redshifts of ≈4.2-5.0. We determine abundances of C, O, Si, S, and Fe, and thereby the metallicities and dust depletions. We find that DLA metallicities at z > 4.5 show a wide diversity spanning ∼3 orders of magnitude. The metallicities of DLAs at 3.7 < z < 5.3 show a larger dispersion compared to that at lower redshifts. Combining our sample with the literature, we find a relatively smooth evolution of metallicity with redshift out to z ∼ 5.3, with a tentative (∼2σ) indication of a slight rise in metallicity at 4.5 < z < 5.3. The relative abundances exhibit C enhancement for both metal-poor and metal-enriched DLAs. In addition, α-element enhancement is evident in some DLAs, including a DLA at z = 4.7 with a supersolar metallicity. Comparing [C/O] and [Si/O] with model predictions, four DLAs in our survey seem consistent with a nonzero Population III contribution (three with ≳30% Population III contribution). Combining our sample and the literature, we find the dust depletion strength and dust-to-metal ratios to correlate positively with the total (gas+solid phase) metallicity, confirming the presence of metal-rich, dusty DLAs even at ∼1 billion years after the Big Bang.