2025ApJ...991L..56L

We present James Webb Space Telescope (JWST) Near Infrared Spectrograph (NIRSpec) and Mid-infrared Instrument integral field spectroscopy of the nearby blue compact dwarf II Zw 40, which has a low metallicity of 25% of solar. Leveraging the high spatial/spectral resolution and wavelength coverage of JWST/NIRSpec, we present robust detections of the 3.3 μm polycyclic aromatic hydrocarbon (PAH) emission on 20 pc scales. The strength of the Pfδ emission relative to the 3.3 PAH feature is significantly stronger than typical higher-metallicity star-forming galaxies. We find that 3.3 μm PAH emission is concentrated near the northern super star cluster and is cospatial with CO gas. A strong correlation exists between the 3.3/11.3 PAH ratio and radiation hardness probed by [Ne III]/[Ne II], providing evidence of photodestruction of PAH molecules in intense radiation environments. Our analysis shows that while the overall PAH fraction is lower in II Zw 40 than in higher-metallicity galaxies, the contribution of the 3.3 μm PAH feature to the total PAH emission is higher. We propose that the PAH size distribution is fundamentally shaped by two competing mechanisms in low-metallicity environments: photodestruction and inhibited growth. Additionally, the high radiation field intensity in II Zw 40 suggests that multiphoton heating of PAHs may be an important effect. As one of the first spatially resolved studies of aromatic emission in a low-metallicity environment, our spectroscopic results offer practical guidance for future observations of the 3.3 μm PAH feature in low-metallicity galaxies using JWST.