2025MNRAS.538.1481M

The study of deuterium fractionation is a valuable tool for reconstructing our chemical history from the early prestellar stages to the formation of planets. In the context of the ALMA Large Programme FAUST, we observed formaldehyde, H$_2$CO, and its singly and doubly deuterated forms, HDCO and D$_2$CO, towards the protostellar cluster VLA1623-2417, on scales of $\sim 2000\!-\!50$ au. Formaldehyde probes the inner envelopes of the protostars VLA1623A, B, and W, the rotating cavities opened by the VLA1623A outflow, and several streamers. The HDCO and D$_2$CO emissions are observed towards VLA1623A, in its outflow cavities, and in one of the streamers. We estimate the gas temperature from the HDCO lines: T$\sim 125$ K towards VLA1623A, indicating hot-corino emission, lower temperatures in the outflow cavities ($20\!-\!40$ K), and in the streamers ($\le 15$ K). The D$_2$CO lines also trace the flattened envelope of VLA1623A, where H$_2$CO and HDCO are fainter. This may be due to D$_2$CO formation on dust grains in the cold prestellar phase, and subsequent photodesorption caused by the enhanced UV flux from two nearby B stars. We inferred the molecular deuteration: [HDCO]/[H$_2$CO] $\sim 0.16$, $\sim 0.07\!-\!0.13$, and $\sim 0.3$; [D$_2$CO]/[H$_2$CO] $\sim 0.003$, $\sim 0.05-0.13$, and $\sim 0.03$ in the hot corino, in the outflow cavities, and in the streamer, respectively. The spatial distribution of D$_2$CO, which points to formation on dust grains, and the similar values of [HDCO]/[H$_2$CO] and [D$_2$CO]/[H$_2$CO] in the components of the system, suggest that deuterium fractionation occurs at the prestellar stage and is then inherited, mostly unaltered, in the protostellar phase.