2025MNRAS.543..146W

Blueshifted absorption is the classic spectroscopic signature of an accretion disc wind in X-ray binaries and cataclysmic variables (CVs). However, outflows can also create pure emission lines, especially at optical wavelengths. Therefore, developing other outflow diagnostics for these types of lines is worthwhile. With this in mind, we construct a systematic grid of 3645 synthetic wind-formed $\mathrm{H\, \alpha }$ line profiles for CVs with the radiative transfer code SIROCCO. Our grid yields a variety of line shapes: symmetric, asymmetric, single- to quadruple-peaked, and even P-Cygni profiles. About 20 per cent of these lines - our 'Gold' sample - have strengths and widths consistent with observations. We use this grid to test a recently proposed method for identifying wind-formed emission lines based on deviations in the wing profile shape: the 'excess equivalent width diagnostic diagram'. We find that our Gold sample can preferentially populate the suggested 'wind regions' of this diagram. However, the method is highly sensitive to the adopted definition of the line profile 'wing'. Hence, we propose a refined definition based on the full width at half-maximum to improve the interpretability of the diagnostic diagram. Furthermore, we define an approximate scaling relation for the strengths of wind-formed CV emission lines in terms of the outflow parameters. This relation provides a fast way to assess whether - and what kind of - outflow can produce an observed emission line. All our wind-based models are open-source and we provide an easy-to-use web-based tool to browse our full set of $\mathrm{H\, \alpha }$ spectral profiles.